2,6,10-TRIMETHYL-5,9-UNDECADIEN-1-OL

  • Name: 2,6,10-TRIMETHYL-5,9-UNDECADIEN-1-OL
  • CAS: 24048-14-4
  • Purity: 99%
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Details

Good factory exports good 2,6,10-TRIMETHYL-5,9-UNDECADIEN-1-OL 24048-14-4

  • Molecular Formula: C14H26O
  • Molecular Weight: 210.36
  • Vapor Pressure: 7.81E-05mmHg at 25°C 
  • Refractive Index: 1.474-1.479 
  • Boiling Point: 305.3°Cat760mmHg 
  • PKA: 15.01±0.10(Predicted) 
  • Flash Point: 109.3°C 
  • PSA： 20.23000 
  • Density: 0.86g/cm3 
  • LogP: 4.08770 

2,6,10-TRIMETHYL-5,9-UNDECADIEN-1-OL(Cas 24048-14-4) Usage

InChI:InChI=1/C14H26O/c1-12(2)7-5-8-13(3)9-6-10-14(4)11-15/h7,9,14-15H,5-6,8,10-11H2,1-4H3/b13-9+/t14-/m1/s1

24048-14-4 Relevant articles

Total Synthesis of (±)-Liphagal via Organic-Redox-Driven Palladium-Catalyzed Hydroxybenzofuran Formation

Tao, Eriko,Inoue, Masaki,Jeong, Taejoo,Kim, In Su,Yoshimitsu, Takehiko

, p. 9064 - 9070 (2020/07/14)

A synthetic route to liphagal, a natural...

Enantioselective inhibition of squalene synthase by aziridine analogues of presqualene diphosphate

Koohang, Ali,Bailey, Jessica L.,Coates, Robert M.,Erickson, Hans K.,Owen, David,Poulter, C. Dale

supporting information; experimental part, p. 4769 - 4777 (2010/09/10)

(Figure Presented) Squalene synthase cat...

Zirconium-catalyzed asymmetric carboalumination of alkenes: ZACA-lipase-catalyzed acetylation synergy

Huang, Zhihong,Tan, Ze,Novak, Tibor,Zhu, Gangguo,Negishi, Ei-Ichi

, p. 539 - 545 (2008/02/08)

ZACA-lipase-catalyzed acetylation tandem...

Enantioselective synthesis of ent-stellettamide A: Asymmetric dipolar cycloadditions with Me3SiCHN2

Whitlock, Gavin A.,Carreira, Erick M.

, p. 2007 - 2022 (2007/10/03)

We report an enantioselective synthesis ...

24048-14-4 Process route

2-Ethoxycarbonyl-6,10-dimethylundeca-5,9-dien-1-saeure-ethylester
25501-67-1

2-Ethoxycarbonyl-6,10-dimethylundeca-5,9-dien-1-saeure-ethylester

(E)-6,10-dimethyl-2-methylene-5,9-undecadien-1-ol
69369-93-3

(E)-6,10-dimethyl-2-methylene-5,9-undecadien-1-ol

(E)-2,6,10-trimethylundeca-5,9-dien-1-ol
58001-88-0,185019-19-6,24048-14-4

(E)-2,6,10-trimethylundeca-5,9-dien-1-ol

Conditions
Conditions Yield
With lithium aluminium tetrahydride; In 1,2-dimethoxyethane; Heating;
2-Ethoxycarbonyl-6,10-dimethylundeca-5,9-dien-1-saeure-ethylester; With sodium hydride; In 2-(2-methoxyethoxy)ethyl alcohol; mineral oil; at 20 ℃; Inert atmosphere; Reflux;
With lithium aluminium tetrahydride; at 20 ℃; Reflux; Inert atmosphere;
(E)-9-iodo-2,6-dimethylnona-2,6-diene
22339-13-5

(E)-9-iodo-2,6-dimethylnona-2,6-diene

(E)-2,6,10-trimethylundeca-5,9-dien-1-ol
58001-88-0,185019-19-6,24048-14-4

(E)-2,6,10-trimethylundeca-5,9-dien-1-ol

Conditions
Conditions Yield
Multi-step reaction with 2 steps
1: 62 percent / ethanol
2: LiAlH4 / 1,2-dimethoxy-ethane / Heating
With lithium aluminium tetrahydride; In 1,2-dimethoxyethane; ethanol;
Multi-step reaction with 4 steps
1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.25 h / 0 °C
1.2: 14 h / 0 - 25 °C
2.1: water; potassium tert -butylate / diethyl ether / 6.5 h / 0 - 25 °C
3.1: 5,5-dimethyl-1,3-cyclohexadiene / 4 h / Reflux
4.1: lithium aluminium tetrahydride / tetrahydrofuran / 1.5 h / 0 - 25 °C
With lithium aluminium tetrahydride; potassium tert-butylate; water; sodium hydride; In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene; diethyl ether; N,N-dimethyl-formamide; mineral oil;

24048-14-4 Upstream products

  • 996-82-7
    996-82-7

    sodium diethylmalonate

  • 22339-13-5
    22339-13-5

    (E)-9-iodo-2,6-dimethylnona-2,6-diene

  • 25501-67-1
    25501-67-1

    2-Ethoxycarbonyl-6,10-dimethylundeca-5,9-dien-1-saeure-ethylester

  • 459-88-1
    459-88-1

    (E)-4,8-dimethylnona-3,7-dien-1-ol

24048-14-4 Downstream products

  • 51513-58-7
    51513-58-7

    (6E)-3,7,11-trimethyl-6,10-dodecadienal

  • 24048-13-3
    24048-13-3

    (R,E)-2,6,10-trimethylundeca-5,9-dienal

  • 1018832-07-9
    1018832-07-9

    (E)-(S)-2,6,10-Trimethyl-undeca-5,9-dienal

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